Journal article
One-pot three-component highly selective synthesis of homoallylboronates by using metal-free catalysis
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Author list: IBRAHEM I, CÓRDOVA A, IBRAHEM I, Lovén Breistein P, CÓRDOVA A
Publication year: 2012
Start page: 5175
End page: 5179
Number of pages: 5
ISSN: 0947-6539
DOI: http://dx.doi.org/10.1002/chem.201103572
View additional information: View in Web of Science™
Abstract
Metal-free selectivity: The first metal-free one-pot three-component highly chemo- and regioselective catalytic synthesis of homoallylboranes using simple N-heterocyclic carbenes (NHC) and amines is presented. The catalytic reaction between B 2(pin) 2, α,β-unsaturated aldehydes and 2-(triphenylphosphoranylidene)acetate esters proceeds through a catalytic metal-free β-boration/Wittig cascade sequence (see scheme). © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
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