Journal article

One-pot three-component highly selective synthesis of homoallylboronates by using metal-free catalysis

Authors/Editors

No matching items found.



Research Areas

No matching items found.


Publication Details

Author list: IBRAHEM I, CÓRDOVA A, IBRAHEM I, Lovén Breistein P, CÓRDOVA A

Publication year: 2012

Start page: 5175

End page: 5179

Number of pages: 5

ISSN: 0947-6539

DOI: http://dx.doi.org/10.1002/chem.201103572

URL: http://www.scopus.com/inward/record.url?eid=2-s2.0-84859903491&partnerID=40&md5=977d80daeded8d23e9d1a5f5d61b7226

View additional information: View in Web of Science


Abstract

Metal-free selectivity: The first metal-free one-pot three-component highly chemo- and regioselective catalytic synthesis of homoallylboranes using simple N-heterocyclic carbenes (NHC) and amines is presented. The catalytic reaction between B 2(pin) 2, α,β-unsaturated aldehydes and 2-(triphenylphosphoranylidene)acetate esters proceeds through a catalytic metal-free β-boration/Wittig cascade sequence (see scheme). © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.


Projects

No matching items found.


Keywords

No matching items found.


Documents

No matching items found.